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The article of chemists - scientists has been published in presticious journal
Sep 13, 2021 | 11:33 / Publications
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The article by general director of the Institute of Catalysis and Inorganic Chemistry named after academician M.Nagiyev ANAS of Azerbaijan academician  Dilgam Taghiyev and group of collaborators from the Institute: Ulviya Mamedova, Mirsalim Asadov, Aygun Isazade, Nizami Zeynalov, Ofeliya Badalova and Shahin Bagirov “Catalytic oxidation of n-hexane on immobilized manganese-containing polymer catalyst” has been published  in journal  Chemical Technology and Metallurgy which is included into international base Web of Science and Scopus.

Novel catalysts, consisting of manganese-containing complex with immobilized quaternized non-crosslinked and cross-linked polymer poly-4-vinylpyridine (P4VP) which was used as a carrier, have been obtained. These catalysts were tested for liquid phase oxidation reaction of n-hexane. The studies were carried out in the temperature range 298 K - 408 K, molar ratios of hexane:oxygen = 1:3.38, and atmospheric pressure. As a result of the catalytic oxidation of n-hexane, the following products were obtained: hexan-1-ol, hexan-2-ol, hexan-3-ol, hexanal and hexanone. It was shown that non-crosslinked and crosslinked N, N’ -methylene-bis-acrylamide (MBAA) manganese-containing (5 wt. %) the polymer catalyst MnP4VP exhibits high activity in the oxidation reaction of n-hexane. The reaction rate constant for the oxidation of n-hexane by oxygen to hexan-1-ol, hexan-2-ol, hexan-3-ol, proceeding with the participation of non-crosslinked and crosslinked MnP4VP catalysts at 303-383 K has been determined.

Journal of Chemical Technology and Metallurgy, Vol. 56, İSS. 5, 2021, 979-987

Web of Science CA -0.8, Scopus, İF-1

CATALYTIC OXIDATION OF N-HEXANE ON IMMOBILIZED MANGANESE-CONTAINING POLYMER CATALYST

Dilgam B. Tagiev, Ulviya A. Mammadova*, Mirsalim M. Asadov, Aygun F. Isazade, Nizami A.Zeynalov, Ofeliya T. Badalova, Shahin T. Bagirov

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