Sep 13, 2021 | 11:33 / Publications
The article by general director of the Institute of Catalysis and Inorganic Chemistry named after academician M.Nagiyev ANAS of Azerbaijan academician Dilgam Taghiyev and group of collaborators from the Institute: Ulviya Mamedova, Mirsalim Asadov, Aygun Isazade, Nizami Zeynalov, Ofeliya Badalova and Shahin Bagirov “Catalytic oxidation of n-hexane on immobilized manganese-containing polymer catalyst” has been published in journal Chemical Technology and Metallurgy which is included into international base Web of Science and Scopus.
Novel catalysts, consisting of manganese-containing complex with immobilized quaternized non-crosslinked and cross-linked polymer poly-4-vinylpyridine (P4VP) which was used as a carrier, have been obtained. These catalysts were tested for liquid phase oxidation reaction of n-hexane. The studies were carried out in the temperature range 298 K - 408 K, molar ratios of hexane:oxygen = 1:3.38, and atmospheric pressure. As a result of the catalytic oxidation of n-hexane, the following products were obtained: hexan-1-ol, hexan-2-ol, hexan-3-ol, hexanal and hexanone. It was shown that non-crosslinked and crosslinked N, N’ -methylene-bis-acrylamide (MBAA) manganese-containing (5 wt. %) the polymer catalyst MnP4VP exhibits high activity in the oxidation reaction of n-hexane. The reaction rate constant for the oxidation of n-hexane by oxygen to hexan-1-ol, hexan-2-ol, hexan-3-ol, proceeding with the participation of non-crosslinked and crosslinked MnP4VP catalysts at 303-383 K has been determined.
Journal of Chemical Technology and Metallurgy, Vol. 56, İSS. 5, 2021, 979-987
Web of Science CA -0.8, Scopus, İF-1
CATALYTIC OXIDATION OF N-HEXANE ON IMMOBILIZED MANGANESE-CONTAINING POLYMER CATALYST
Dilgam B. Tagiev, Ulviya A. Mammadova*, Mirsalim M. Asadov, Aygun F. Isazade, Nizami A.Zeynalov, Ofeliya T. Badalova, Shahin T. Bagirov