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Chemists improved the synthesis of laser materials
Jan 09, 2020 | 13:54 / Interesting information
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The practical use of rare-earth oxysulfides is limited by the difficulties associated with their synthesis.

Scientists of the Department of Inorganic and Physical Chemistry at TomSU proposed a synthesis method - the use of rare-earth elements as a precursor. To obtain the desired compound, the authors prepare an aqueous solution of nitrates, which contains all the necessary components, and then, by coprecipitation, transfer into a solid solution of sulfates of rare-earth elements. After chemical homogenization, during which lanthanide ions — cerium, europium, dysprosium, and erbium — are introduced into the reaction mixture, the resulting compounds are reduced in a hydrogen atmosphere and sulfidized in an H2S atmosphere.

The authors report that the crystal structure of the synthesized compounds has trigonal symmetry.

The work has been published in the Journal of Solid State Chemistry.

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